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Optical sorting technology for waste management from the Boukhadra iron ore mine (NE Algeria)

Abstract

Mining processes in the iron ore mine of Boukhadra, Tebessa (NE Algeria) generated thousands of tons of mining wastes every year, which represents a real threat to the environment, leading to hazardous effects for the resident population of the region. The aim of this study is the selective sorting of the Boukhadra mining wastes for valorization. This will facilitate the recycling of the mineral substances (limestone, iron, marls) on the one hand and it makes it possible to minimize the volume of stocks and their environmental impacts on the other hand. To do this, and taking into account the chemical properties of wastes, we recommend an optical separation management using a color camera and a microprocessor linked to the ejection system (valve or pump), the color measurement tests performed on Boukhadra waste rocks samples using Matlab codes converted from Algorithms showed that each rock has a specific color (Red Green Blue value) or RGB. For this purpose, the use of three optical separators that sort according to algorithmic commands (RGB interval) will contribute to the separation of the Boukhadra mining wastes and consequently simplify their reuse.

Keywords:
Boukhadra mine; environment; optical sorting; recycling; valorization; mine wastes

1. Introduction

The releases from mining are a potential negative source for the environment, sludge dumping, mine drainage, soil, air pollution and many other threatening effects to both environment and human lives (Bouzahzah et al., 2014BOUZAHZAH, H.; BENZAAZOUA, M. ; BUSSIERE, B. ; PLANTE, B. Revue de littérature détaillée sur les tests statiques et les essais cinétiques comme outils de prédiction du drainage minier acide. Déchets Sciences et techniques, v. 66, p. 14-31. 2014.; Benselhoub et al., 2015aBENSELHOUB, A.; KHARYTONOV, M.; BOUABDALLAH, S.; BOUNOUALA, M.; IDRES, A.; BOUKELLOUL, M. Bioecological assessment of soil pollution with heavy metals in Annaba (Algeria). Studia Universitatis “Vasile Goldiş”, Seria Ştiinţele Vieţii, v. 25, n. 1, p.17-22, 2015.; Stankevich et al., 2015STANKEVICH, S.; TITARENKO, O.; KHARYTONOV, M.; BENSELHOUB, A.; BOUNOUALA, M..; CHAABIA, R.; BOUKELOUL, M. L. Mapping of urban atmospheric pollution in the northern part of Algeria with nitrogen dioxide using satellite and ground-truth data. Studia Universitatis “Vasile Goldiş”, Seria Ştiinţele Vieţii, v. 25, n. 2, p. 87-92, 2015.; Idres et al., 2017IDRES, A.; ABDELMALEK, C.; BOUHEDJA, A.; BENSELHOUB, A.; BOUNOUALA, M. Valorization of mining waste from Ouenza iron ore mine (eastern Algeria). REM-International Engineering Journal, v. 70, n. 1, р. 85‒92, 2017.). The management or the zero-waste goal is based on source reduction, repair, reuse and recycling (Topanou, 2012TOPANOU, K. A. N. Gestion des déchets solides ménagers dans la ville d'Abomey-Calavi (Bénin): caractérisation et essais de valorisation par compostage. 2012. Thèse (Doctorat en Chimie de l’environnement, Doctorat en Chimie des déchets) - Université d’Abomey-Calavi, Godomey, Université d’Aix Marseille, Marseille, 2012.). Going back to the history of ore valorization, a lot of sorting techniques have been used, such as, mechanical sorting (trommel), electrical sorting (Foucault current), magnetic sorting (magnetic separator), radiometric sorting (radius γ) and optical sorting (camera).

The concept of optical separation has already been used for the sorting of seed, wheat, coffee, household wastes (plastics, glasses, papers). Today it is widely used for the sorting of mining wastes. An example of the newly developed optical system at Comex (an optical sorter) allows the identification and separation of the different mineral particles according to their color, resulting in a product of high purity ranging from 99 to 99.9% (Kolacz, 2012KOLACZ, J. Advanced sorting technologies and its potential in mineral processing. AGH Journal of Mining and Geoengineering, v. 36, n. 4, p. 39-48, 2012.).

As a result, based on the interaction results of light with minerals (color), optical separators can play a very important role in the field of integrated mine waste management.

2. Overview on Boukhadra mining wastes

The Boukhadra mine is located in the Jebel Boukhadra Mountain at an elevation of 850 m, with the Mount of Boukhadra constituting the highest part (the peak) with an altitude of 1463 m (ArcelorMittal, 2012ARCELORMITTAL. Rapport géologique actualisé Année 2012. Rapport inédit. Division Etudes et Développement. Tébessa, Mine de Boukhadra: ArcelorMittal, 2012. p. 20.). Figure 1 represents a general view of Boukhadra iron mine and wastes generated during the different mining processes.

Figure 1
General view on the mining wastes from the Boukhadra mine.

Downstream of the mountain, we find the Boukhadra village with more than 11000 inhabitants. The mine case of this study has been mined since Roman times for the extraction of copper, after which exploitation was conducted for zinc and other polymetals. From 1926 until today, the mine exploits the iron ore of the hematite type by two methods: open and underground (ArcelorMittal, 2012ARCELORMITTAL. Rapport géologique actualisé Année 2012. Rapport inédit. Division Etudes et Développement. Tébessa, Mine de Boukhadra: ArcelorMittal, 2012. p. 20.). According to their use, iron ore is the most required element in the world, as well as in Algeria. To satisfy the demand for this mineral resource (iron and steel industry, cement plant), the mine must increase the rate of prospecting and exploitation works, which generates, of course, thousands of tons of mining wastes, stored in the form of piles.

This mining waste occupies a large area, and hinders exploitation (truck circulation), and residents are affected by the sliding of the blocks from the mining wastes. Moreover, this waste generates air, water and ground pollution in the form of dust, runoff of the leaching water from mining wastes (especially during rainfall), and infiltration of water contaminated with iron in the soil which consequently affects living beings (humans, wildlife and flowers). The random storage of the mining waste deteriorates the panorama of the region and disturbs the natural life (environment). Some environmental impacts of mining wastes from the Boukhadra mine are discussed in (ArcelorMittal, 2014ARCELORMITTAL. Rapport géologique actualisé Année 2014. Rapport inédit. Division Etudes et Développement. Tébessa, Mine de Boukhadra: ArceloMittal, 2014. p. 39.).

3. Characterization of Boukhadra mining wastes

3.1 Chemical analysis of mining wastes

Two varieties of mining wastes are found in the stockpiles of the Boukhadra mine; waste rocks and other mine wastes (low grade iron ore resulting from the extraction process). Their chemical composition was determined by an XRF analyzer in the Center for the Study and Technological Services of Construction Materials Industry (CSTSCMI) - Boumerdes (Table 1).

Table 1
Chemical analysis by XRF of mining wastes from the Boukhadra mine.

3.2 Atomic adsorption spectroscopy (AAS) analysis

Atomic Absorption Spectrometry (AAS) is an analytical technique whose objective is to measure the amount of chemical elements (metals) present in a material while measuring the radiation absorbed by this material (García and Báez, 2012GARCÍA, R.; BÁEZ, A. P. Atomic absorption spectrometry (AAS). In: FARRUKH, M. A. (ed.). Atomic absorption spectroscopy. [S. l.]: IntechOpen, 2012. p. 12-29.). The analysis by SAA of the Boukhadra iron mining wastes was performed at the Office of Geologic and Mining Research (OGMR) - Boumerdes (Table 2).

Table 2
Atomic adsorption spectroscopy (AAS) analysis of the Boukhadra mining wastes.

3.3 Scanning electron microscope (SEM) analysis

Scanning Electron Microscopy (SEM) is an analytical technique that produces high-resolution images of the surface of a material. When an electron beam sweeps the surface of a sample, this latter emits certain particles; and these particles are analyzed by different detectors and construct a three-dimensional image (Errais, 2011ERRAIS, E. Réactivité de surface d'argiles naturelles: Etude de l'adsorption de colorantsanioniques. 2011. Thèse (Doctorat Geochimie de l’Environnement) - Universite de Strasbourg, Strasbourg, 2011.).

The analysis by SEM of Boukhadra waste rocks was done at the National High School of Mining and Metallurgy (NHSMM) Annaba. The SEM analysis shows cut limestone grains (CaCO3), which confirms that the wastes have not undergone acid attack. There are also, microorganisms, silica spherules (SiO2), alumina grains (bauxite Al2O3) sub-rounded and hematite crystallite debris (Fe2O3) from which we can guess by the hexagonal forms, that the grain forms indicate prior mechanical treatment because the fragmentation is visible by SEM. In addition, around the grains, other elements were detected by SEM, namely, P, Mg, Ba (Figure 2).

Figure 2
SEM Photomicrographs for different magnifications of the Boukhadra waste rocks (a: X 400, b: X 3000) and associated spectra.

4. Analysis of drainage water

Three (3) samples of water were collected from three (3) different zones near the Boukhadra iron mine for a characterization of their nature. A chemical analysis of the samples was carried out at the Society of Water and Sanitation of Algiers (SWSAL), and the results are given in Table 3.

Table 3
Analysis of mine drainage water from the Boukhadra.

Overall, these analysis results show unacceptable values in relation to the required standards (Official Journal of Algeria 2011). However, some COD and BOD5 values are well above the allowable threshold and the ratio of: COD/DOB5=37.53/7.5=5.004>3.This indicates a high rate of organic matter in this water. Also, this effluent is not degradable (difficult to treat).

High levels of Sulfates and Ammonium (NH4+) are also noted, as well as the presence of heavy metals (lead, zinc). Since the high content of metals interferes in the biological treatment of water, they also pose a direct danger to human health. All this shows a chemical contamination of the Boukhadra site water, and consequently, the soils that are in contact; this is in direct correlation with the high contents of ferrous elements (Fe2O3) and in Barium (BaSO4).

In fact, water pollution can also lead to soil contamination, and this will affect the water table, the quality of surface and groundwater water, which have direct impacts on animals (polluted grass) and therefore the human health (ArcelorMittal, 2014ARCELORMITTAL. Rapport inédit. Tébessa, Mine de Fer Boukhadra: ArcelorMittal, 2014. 48 p.).

5. Soil analysis

Soil samples were collected in three sites at Boukhadra village closed to the mine, five subsamples were taken in a depth of 0-5 cm within each plot in order to obtain a representative sample, as close as possible to the center of the plot in a homogeneous pedological area (Benselhoub et al., 2015bBENSELHOUB, A.; KHARYTONOV, M.; BOUNOUALA, M.; CHAABIA, R.; BADJOUDJ, S. Estimation of soil's sorption capacity to heavy metals in Algerian megacities: case of Algiers and Annaba. INMATEH-Agricultural Engineering, v. 46, n. 2, p. 147-154, 2015.). The soil chemical analyses are presented in the Tables 4 and 5.

Table 4
Chemical analysis of soils from the Boukhadra village.
Table 5
Analysis by AAS of soils from the Boukhadra village.

From the previous results, we observe that the soil of Boukhadra is a little polluted by heavy metals specially, the lead metal (Pb) and a variable concentration of iron. This is due to the infiltration of water contaminated by the iron on the Boukhadra soil, the high rate of silica shows that the soils of Boukhadra are acidic.

6. Manual sorting of Boukhadra iron mining wastes

Before proceeding with the optical sorting of Boukhadra mining wastes, we made a manual sorting of these wastes according to the mineral colors (Figure 3). It is clear that the mineralogical composition consists mainly of: limestone, hematite, yellow and gray marl (Rouaiguia et al., 2017ROUAIGUIA, I.; BOUNOUALA, M.; ABDELMALEK, C.; IDRES, A. Valorization of waste rocks from Boukhadra iron ore mine for better environmental management. Natsional'nyi Hirnychyi Universytet. Naukovyi Visnyk, n. 6, p. 60-67, 2017.), and the presence of these minerals is confirmed by the XRD analysis.

Figure 3
Manual sorting of mining waste from Boukhadra.

6.1 XRD Analysis of the mining wastes

The analysis by X-ray diffraction of the Boukhadra waste rocks performed at (OGMR Boumerdes) are given in Figures 4, 5, 6 and 7.

Figure 4
XRD spectra of limestone.
Figure 5
XRD spectra of iron.
Figure 6
XRD spectra of gray marl.
Figure 7
XRD spectra of yellow marl.

6.2. Chemical analysis of the mining wastes

The chemical composition of the mining wastes given in the Table 6 was carried out by the XRF analyzer at (CSTSCMI - Boumerdes).

Table 6
Chemical analysis of mining wastes at the Boukhadra mine.

According to the chemical analyses of these samples, the iron content is 34.32% Fe2O3; 21.14% SiO2; 8.22% CaO and 3.61% Al2O3. Limestone is constituted of49.87% CaO. Yellow marl is composed of 46.26% SiO2 and 18.45% CaO against 34.45% SiO2 and 25.82% CaO in the gray marl.

For better understanding of the qualitative and quantitative aspect of this material, taking into account the color of the minerals, we proposed the management of these mining wastes by optical sorting (colorimetric separation).

7. Management of mining wastes by optical sorting

Ore treatment and integrated management of mining wastes play a key role in the field of mining industry by reducing the large volumes stored on the tile and by facilitating their reuse in various economic sectors, and in the restoration or the rehabilitation of mine sites (Boudra et al., 2015BOUDRA, L.; DELECROIX, B.; BÉGUIN, P. La prévention dans le green business à l'échelle des proximités territoriales Une question de performance globale pour les centres de tri des déchets d’emballages ménagers. In: CONGRÈS INTERNATIONAL SOCIÉTÉ D’ERGONOMIE DE LANGUE FRANÇAISE, 50., 2015, Paris. Actes […]. Paris: SELF, 2015. p. 1-7.). To do this, colorimetric measurements are performed on different samples of the Boukhadra mining wastes for their separation by an optical sorter.

7.1 Principle of optical sorting

According to Manouchehri, 2003MANOUCHEHRI, H. Sorting: possibilitis, limitations and future. In: KONFERENS I MINERALTEKNIK 2003, Luleå, Sweden = CONFERENCE IN MINERAL PROCESSING. Proceedings […]. Swedish: Mineral Processing Research Association, 2003., the optical sorting process is one of the most efficient and economical cost-saving techniques that can be used for secondary wastes treatment, separation and recycling. This will minimize investment costs, limit the environmental impacts of mining wastes and improve the quality of the ore. The optical separator is mainly constituted of the following sections (Suhasaria and Pathak, 2012SUHASARIA, A.; PATHAK, K. Application of colour based ore sorting through image processing. Indian Mining and Engineering Journal, 2012.):

Feeding: The crushed feed material is transported to the point where the optical data is collected.

Collecting optical data: The ore must pass through an optical sensor system (color camera), the reflected light of each particle is detected and processed.

Optical data processing: Optical data processing is performed by an electronic processor; appropriate signals are transmitted to the mechanical system for the separation of materials.

Mechanical separation system: according to the instructions given by the processor, the mechanical separation system consists of a valve or a compressed air rejecter, which sorts.

More illustrations are given in Figure 8.

To determine the RGB of mineral images to be separated we used the following Algorithm:

Figure 8
Functional principle of the optical sorter (Von Ketelhodt and Vollmar, 2012FREIHERR VON KETELHODT, L. G. V. Beneficiation of Witwatersrand typegold ores by means of optical sorting. 2012. Dissertation (Master of Science in Engineering) - Faculty of Engineering and the Built Environment, University of the Witwatersrand, Johannesburg, 2012.).

Begin

Load image (IMG)

Read red color of image (IMG) and save it in new image (RIMG)

Read green color of image (IMG) and save it in new image (GIMG)

Read blue color of image (IMG) and save it in new image (BIMG)

Calculate the mean of each image (MRIMG, MGIMG and MBIMG)

Showing all images (IMG, RIMG, GIMG, BIMG)

End

8. Results and discussions

Tests by Matlab codes were performed to determine the RGB of the several images from Boukhadra mining wastes; the results are given in the Table 7:

Table 7
Determination of the RGB of images from the Boukhadra mining wastes.

The scheme presented in Figure 9 is a proposed flow sheet for the management of the Boukhadra mining wastes.

Figure 9
Diagram of optical sorting for Boukhadra mining wastes.

For the management of optical sorter ejection system according to the RGB values, we use the following Algorithms:

For the management of optical sorter ejection system according to the RGB values, we use the following Algorithms:

Optical sorting 1

Begin

Load image (IMG)

Read red color of image (IMG) and save it in new image (RIMG)

Read green color of image (IMG) and save it in new image (GIMG)

Read blue color of image (IMG) and save it in new image (BIMG)

Calculate the mean of each image (MRIMG, MGIMG, and MBIMG)

The image is defined like this algorithm

If (the average of the red component (MRIMG) varies between 93 and 98 and the average of the green component (MGIMG) varies between 91 and 99 and the average of the blue component (MBIMG) varies between 75 and 82) Or (the average of the red component (MRIMG) varies between 99 and 110 and the average of the green component (MGIMG) varies between 102 and 113 and the average of the blue component (MBIMG) varies between 87 and 107) then

Showing that the image is ‘Limestone and Gray marl';

Call optical sorting 2

Else if (the average of the red component (MRIMG) varies between 60 and 69 and the average of the green component (MGIMG) varies between 49 and 57 and the average of the blue component (MBIMG) varies between 40 and 50) Or (the average of the red component (MRIMG) varies between 148 and 156 and the average of the green component (MGIMG) varies between 128 and 137 and the average of the blue component (MBIMG) varies between 84 and 90) then

Showing that the image is 'Iron and Yellow marl';

Call optical sorting 3

End

Showing the color of image (IMG)

End

Optical sorting 2

Begin

Load image (IMG)

Read red color of image (IMG) and save it in new image (RIMG)

Read green color of image (IMG) and save it in new image (GIMG)

Read blue color of image (IMG) and save it in new image (BIMG)

Calculate the mean of each image (MRIMG, MGIMG, and MBIMG)

If (the average of the red component (MRIMG) varies between 93 and 98 and the average of the green component (MGIMG) varies between 91 and 99 and the average of the blue component (MBIMG) varies between 75 and 82) then

Showing that the image is ‘Limestone’

Else if (the average of the red component (MRIMG) varies between 99 and 110 and the average of the green component (MGIMG) varies between 102 and 113 and the average of the blue component

(MBIMG) varies between 87 and 107) then

Showing that the image is ' Gray marl';

End

End

Optical sorting 3

Begin

Load image (IMG)

Read red color of image (IMG) and save it in new image (RIMG)

Read green color of image (IMG) and save it in new image (GIMG)

Read blue color of image (IMG) and save it in new image (BIMG)

Calculate the mean of each image (MRIMG, MGIMG, and MBIMG)

If (the average of the red component (MRIMG) varies between 60 and 69 and the average of the green component (MGIMG) varies between 49 and 57 and the average of the blue component (MBIMG) varies between 40 and 50) then

Showing that the image is 'iron ‘;

Else if (the average of the red component (MRIMG) varies between 148 and 156 and the average of the green component (MGIMG) varies between 128 and 137 and the average of the blue component (MBIMG) varies between 84 and 90) then

Showing that the image is ’ Yellow marl';

End

End

9. Benefits of the proposed method

Generally, sorting is an intermediate and indispensable step for waste treatment; its main purpose is to transform a group of mixed wastes into several categories easily recyclable. Similarly, mineral sorting is a proven technology in many industries around the world. It uses a variety of electronic sensors combined with high-speed processors that can be programmed to recognize certain characteristics of the ores: color, radiation, density, conductivity, magnetization, etc. A mechanical ejection system is then activated by the processor that ejects the particles from the feed (Murphy, Zyl and Domingo, 2012MURPHY, B.; ZYL, J. VAN; DOMINGO, G. Underground preconcentration by ore sorting and coarse gravity separation. In: NARROW VEIN MINING CONFERENCE, 2012, Peth, Australia. Proceedings […]. Perth, WA: Australasian Institute of Mining and Metallurgy (AusIMM), 2012.).

Moreover, optical and other sensor-based sorting techniques for materials have made rapid progress in Europe over the last 10 years (Wotruba, 2006WOTRUBA, H. Sensor Sorting Technology - is the minerals industry missing a chance? In: INTERNATIONAL MINERAL PROCESSING CONGRESS, 23., 2006, Istanbul. Proceedings […]. Istanbul, Turkey: Promed Advertising, 2006. p. 21-30.). They are widely used in several mining industries other than phosphates to reduce wastes. Only one application in the phosphate industry was used by a phosphate mine in the early 1980’s in western United States. Other phosphate extraction companies have recently shown interest in optical sorting and have conducted a prefeasibility test at the laboratory scale (Daoudi, Kukenska, 2013DAOUDI, R.; KUKENSHA, V. Utilization of optical sorting technique in the phosphate industry. In: CENTRAL FLORIDA 2013 SYMPOSIUM, Sheraton Sand Key, 2013, Clearwater, Florida. Proceedings […]. [S. l.: s. n.], 2013. p.9.).

Therefore, the implementation of an optical separator in the mine site will have many benefits; this separation technique is fast, simple, malleable, economic and less polluted process (little dust because the particle size of minerals to be separated is ≥ 10 mm). It doesn’t require large investments, and also saves travel expenses, loading, transport and treatment of mining wastes. Besides, it contributes to the selective sorting of different types of rock according to their chemical characteristic, which are composition and color (limestone, iron ore, gray marl and yellow marl). This will facilitate their recycling and reuse in the different sectors, (construction aggregates, cement, paint, ceramics, iron and steel, etc.).

To do this, the optical sorting of mining wastes from the Boukhadra mine makes it possible to dispose of unneeded materials (mine wastes), to free up the areas occupied by these latter and consequently to prevent environmental problems related to water and soil pollution following the leaching of mining wastes, dust, falling blocks to residents located downstream of the mine, etc.

10. Conclusions

The Boukhadra iron ore mine is operated by a combined method (open-pit and underground) which generates thousands of tons of mine wastes per year (waste rocks and others) that really causes major environmental problems: air, water or soil pollution, erosion and mine drainage, etc.

In order to assess their effects, representative samples of mine wastes, water and soil taken from the studied area reveal a contamination by dissolved iron due to the leaching of mining wastes.

To counter the phenomenon of mining drainage and avoid the erosion of mining wastes stored on the side of the mountain near the Boukhadra village residents, valorization of mining wastes can contribute to the reduction of stacked volumes by use of the optical technique.

Tests in color measurements show that there is a possibility for the management of the Boukhadra waste rocks based on color difference (RGB values of minerals).

Ore sorting technology is a less polluted process, which will contribute to the removal of the unneeded discharges and will also facilitate the recycling and the reuse of Boukhadra mining wastes.

Acknowledgments

This study was carried out in the Valorization of Mining Resources and Environment Laboratory (LAVAMINE), Mining Department, Badji Mokhtar University, Annaba, Algeria. The authors would like to thank all colleagues who contributed to the realization of the present work, and especially to Dr.Derradji Nada.

References

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Publication Dates

  • Publication in this collection
    20 Dec 2021
  • Date of issue
    Jan-Mar 2022

History

  • Received
    18 Dec 2017
  • Accepted
    14 June 2018
Fundação Gorceix Rua Carlos Walter Marinho Campos, 56, Cep: 35400-000, Tel: (31) 3551-4730 - Ouro Preto - MG - Brazil
E-mail: editor@rem.com.br