Sustainable use of extracts of animal and vegetable origin as additives to prevent corrosion in the fertilizer chain

Ammirati, Ana Cristina; Nascimento, Carmem Célia Francisco do

Acessibilidade / Reportar erro

Brasil

Español English

sumário « anterior atual seguinte »

Sumário

Artigos • Matéria (Rio J.) 27 (1) • 2022 • https://doi.org/10.1590/1517-7076-RMAT-2021-44965 copy

Sustainable use of extracts of animal and vegetable origin as additives to prevent corrosion in the fertilizer chain

Authorship SCIMAGO INSTITUTIONS RANKINGS

ABSTRACT

The fertilizer industry in Brazil has been growing at an accelerated pace driven by the increase in The fertilizer industry in Brazil has been growing at an accelerated pace driven by the increase in agribusiness, however this industrial chain involves continuous operation in an aggressive environment, generating stops for corrective maintenance due to the wear and tear of the industrial chain due to corrosion. In recent years, the cost of the industry with maintenance has reached 4% in relation to gross sales. With the objective of reducing this cost and aiming at sustainability, new techniques have been invested to protect the production plant against the severe effects of corrosion, aiming at increasing production, reducing maintenance stops, extending the plant’s useful life and decrease in toxic waste. Several studies with extracts of animal and plant origin have been carried out as possible corrosion protection additives for metallic surfaces, as they are considered environmentally correct, forming a film at the corrosive metal-medium interface. This work shows corrosion studies by electrochemical techniques on 1020 steel containing extracts of Struthio Camelus (ostrich), Crolatus Durissus (rattlesnake) and Elaeis Guineensis (palm and palm kernel) in a solution of Sodium Chloride (NaCl) and 3% Urea. The results indicated a significant decrease in the corrosion rates of steel when submitted to 3% Urea in the presence of all extracts, when compared with the results obtained in the presence of 3% NaCl. Carbon steel with Crolatus Durissus extract in Urea 3% showed a corrosion rate of 0.003 mm/year, the best behavior in this medium, followed by Elaeis Guineensis extract, 0.009 mm/year. Steel in the presence of Elaeis Guineensis with 3% NaCl showed a corrosion rate of 0.05 mm/year, being the best result for the medium.

Keywords
Fertilizer; Urea, Electrochemical Corrosion; Struthio Camelus; Crolatus Durissus

ELEMENTO	COMPOSIÇÃO
Carbono	0,18 a 0,23%
Manganês	0,30 a 0,60%
Enxofre	0,05%
Fósforo	0,014%
Ferro	restante da composição

EXTRATO	COMPOSIÇÃO	LOCAL DO EXTRAÇÃO	REFERÊNCIA BIBLIOGRÁFICA
Óleo de Palma	44% Ácido Palmítico 40% Ácido Oleico	Fruto da palmeira	[¹²[12] BELGACEM, M.N., GANDINI, A. Monomers, Polymers and Composites from Renewable Resources, Amsterdam: Elsevier, 2008.,¹³[13] SALIMON, J., SALIH, N., YOUSIF, E., “Biolubricants: Raw materials, chemical modifications and environmental benefits”, Eur. J. Lipid Sci. Technol., v.112, n.5, pp. 519–530, 2010. https://doi.org/10.1002/ejlt.200900205 https://doi.org/https://doi.org/10.1002/... ,¹⁵[15] FAYOMI, O.S.I., POPOOLA, A.P.I.,“The Inhibitory Effect and Adsorption Mechanism of Roasted Elaeis guineensis as Green Inhibitor on the Corrosion Process of Extruded AA6063 Al-Mg-Si Alloy in Simulated Solution”, Silicon, v. 6, pp. 137–143, 2014. https://doi.org/10.1007/s12633-014-9177-3 https://doi.org/https://doi.org/10.1007/... ]
Palmiste	47% Ácido Láurico 16% Ácido Oleico	Amêndoa da palmeira	[¹²[12] BELGACEM, M.N., GANDINI, A. Monomers, Polymers and Composites from Renewable Resources, Amsterdam: Elsevier, 2008.,¹³[13] SALIMON, J., SALIH, N., YOUSIF, E., “Biolubricants: Raw materials, chemical modifications and environmental benefits”, Eur. J. Lipid Sci. Technol., v.112, n.5, pp. 519–530, 2010. https://doi.org/10.1002/ejlt.200900205 https://doi.org/https://doi.org/10.1002/... ,¹⁵[15] FAYOMI, O.S.I., POPOOLA, A.P.I.,“The Inhibitory Effect and Adsorption Mechanism of Roasted Elaeis guineensis as Green Inhibitor on the Corrosion Process of Extruded AA6063 Al-Mg-Si Alloy in Simulated Solution”, Silicon, v. 6, pp. 137–143, 2014. https://doi.org/10.1007/s12633-014-9177-3 https://doi.org/https://doi.org/10.1007/... ]
Óleo de Avestruz	23%Ácido Palmítico 40% Ácido Oleico	Tecido adiposo do abdômen	[¹²[12] BELGACEM, M.N., GANDINI, A. Monomers, Polymers and Composites from Renewable Resources, Amsterdam: Elsevier, 2008.,¹⁷[17] PONPHAIBOON J., LIMMATVAPIRAT, S, CHAIDEDGUMJORN, A., et al, “Physicochemical property, fatty acid composition, and antioxidant activity of ostrich oils using different rendering methods”, Food Science and Technology, v. 93, pp. 45–50, 2018.,¹⁸[18] BASUNY, A.M.M., ARAFAT, S.M., NASEF, S.L., “Utilization of ostrich oil in foods”, International Research Journal of Biochemistry and Bioinformatics, v. 2, n. 8, pp. 199–208, 2011.]
Banha de Avestruz	20%Ácido Palmítico 31% Ácido Oleico	Tecido adiposo do abdômen	[¹²[12] BELGACEM, M.N., GANDINI, A. Monomers, Polymers and Composites from Renewable Resources, Amsterdam: Elsevier, 2008.,¹⁷[17] PONPHAIBOON J., LIMMATVAPIRAT, S, CHAIDEDGUMJORN, A., et al, “Physicochemical property, fatty acid composition, and antioxidant activity of ostrich oils using different rendering methods”, Food Science and Technology, v. 93, pp. 45–50, 2018.,¹⁸[18] BASUNY, A.M.M., ARAFAT, S.M., NASEF, S.L., “Utilization of ostrich oil in foods”, International Research Journal of Biochemistry and Bioinformatics, v. 2, n. 8, pp. 199–208, 2011.]
Óleo de Cobra	alfa-linolênico	Carne	[¹²[12] BELGACEM, M.N., GANDINI, A. Monomers, Polymers and Composites from Renewable Resources, Amsterdam: Elsevier, 2008.,¹³[13] SALIMON, J., SALIH, N., YOUSIF, E., “Biolubricants: Raw materials, chemical modifications and environmental benefits”, Eur. J. Lipid Sci. Technol., v.112, n.5, pp. 519–530, 2010. https://doi.org/10.1002/ejlt.200900205 https://doi.org/https://doi.org/10.1002/... ]

EXTRATO	COMPOSIÇÃO QUÍMICA	R_S (Ωcm²)	R_CT (Ωcm²)	C_DL (F.cm^-2)	X ²
Sem Extrato	----------------------	8,84	1.934,21	1,94. 10^–3	–
Óleo de Palma	44% Ácido Palmítico 40% Ácido Oleico	35,9	3,34.10³	78,5.10^–9	0,013
Palmiste	47% Ácido Láurico 16% Ácido Oleico	14,7	1.302,5.10³	2,84. 10^–3	0,020
Banha de avestruz	20%Ácido Palmítico 31% Ácido Oleico	10,5	364	314.10^–6	0,069
Óleo de Cobra	alfa-linolênico	12,1	298	25,1 10^–6	0,82

EXTRATO	βa (V/dec)	βc (V/dec)	\|Ecorr\| (V)	icorr (A)	TC (mm/ano)	R_P (Ω)
Sem Extrato	0,482	0,069	0,654	0,076	0,0882	3.447,8
Óleo de Avestruz	0,170	12,491	0,522	0,329	0,3825	1.977,7
Banha de Avestruz	0,200	0,086	0,611	0,179	0,2081	1.461,2
Óleo de Cobra	0,103	0,145	0,648	0,128	0,1487	2.041,0
Palmiste	0,269	0,439	0,695	0,108	0,1259	6.686,5
Palma	10,699	1,5418	0,155	3,48. 10^–7	0,0048	1,68.10⁺⁶

EXTRATO	COMPOSIÇÃO QUÍMICA	R_s (Ωcm²)	R_ct (Ωcm²)	f_max (Hz)	C_dl (F.cm^–2)
Sem Extrato	----------------------	2.190,41	7.527,85	37.276	6,98
Óleo de Avestruz	23%Ácido Palmítico 40% Ácido Oleico	33.326,72	1,98. 10⁵	138,95	8,44.10^–4
Banha de Avestruz	20%Ácido Palmítico 31% Ácido Oleico	5.661,91	2,78. 10⁵	71,96	2,64.10^–4
Palmiste	47% Ácido Láurico 16% Ácido Oleico	55.723,82	2,41.10⁵	7.196,96	3,87.10^–2
Óleo de Palma	44% Ácido Palmítico 40% Ácido Oleico	20.582,61	2,78.10⁵	7.196,96	2,79.10^–2
Óleo de Cobra	alfa-linolênico	5,70	4,91.10⁵	7,96	1,62.10^–5

EXTRATO	βa (V/dec.)	βc (V/dec.)	\|E_corr\| (V)	i_corr (A)	TC (mm/ano)	RP (Ω)
Sem Extrato	68,39	1,77	0,507	0,639	0,742	11.752
Banha de Avestruz	1,03	12,67	0,135	0,008	0,010	301.010
Óleo de Avestruz	1,59	21,90	0,158	0,019	0,023	206.120
Palmiste	13,32	15,40	0,144	0,012	0,014	253.490
Palma	12,00	12,87	0,123	0,009	0,011	297.890
Cobra	0,59	0,67	0,109	0,003	0,003	546.760

METAL	ELETRÓLITO	EXTRATOS	TAXA DE CORROSÃO	\|ECORR\|	ICORR
METAL	ELETRÓLITO	EXTRATOS	(MM/ANO)	(V)	(A)
Aço 1020	NaCl a 3%	Sem	0,088	0,654	0,076
Aço 1020	NaCl a 3%	óleo de Avestruz	0,383	0,522	0,329
Aço 1020	NaCl a 3%	Banha de Avestruz	0,208	0,611	0,179
Aço 1020	NaCl a 3%	Palma	0,005	0,155	0,04
Aço 1020	NaCl a 3%	Palmiste	0,126	0,695	0,108
Aço 1020	NaCl a 3%	Cobra	0,149	0,648	0,128

EXTRATO	TAXA DE CORROSÃO	\|ECORR\|	ICORR
EXTRATO	(MM/ANO)	(V)	(A)
Banha de Avestruz	0,010	0,135	0,008
Óleo de Avestruz	0,023	0,158	0,019
Palmiste	0,014	0,144	0,012
Palma	0,011	0,123	0,009
Cobra	0,003	0,109	0,003

Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro, em cooperação com a Associação Brasileira do Hidrogênio, ABH2 Av. Moniz Aragão, 207, 21941-594, Rio de Janeiro, RJ, Brasil, Tel: +55 (21) 3938-8791 - Rio de Janeiro - RJ - Brazil
E-mail: revmateria@gmail.com

Acompanhe os números deste periódico no seu leitor de RSS

[1] e-mail: ammirati.ana@acad.ifma.edu.br, carmemfn@ifma.edu.br