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Stereoselective synthesis of carbohydrate-based fused bicyclic delta-lactones

We describe in the present work the synthesis of carbohydrate-based chiral delta-lactones by regio- and stereoselective radical cyclization reactions. The configuration of the newly stereogenic center was found to depend on the structure of the carbohydrate moiety.

radical cyclization; carbohydrate and delta-lactones


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