Alcohol
|
|
|
|
|
|
|
|
1-propanol |
alcoholic, pungent |
8.89. 106 ± 0.6.106a
|
2.47. 106 ± 0.6. 106b
|
3.94. 106 ± 0.6. 105b
|
<600 |
548 |
MS |
7-Octen-2-ol, 2,6-dimethyl- |
|
6.69.106 ± 0.4.106
|
nd |
nd |
<600 |
- |
MS |
1-Butanol, 2-methyl |
|
3.60. 106 ± 0.6. 106
|
nd |
nd |
751 |
728 |
MS+LRI |
1-Butanol (Butyl alcohol) |
alcoholic |
4.96. 105 ± 0.5. 105
|
nd |
nd |
778 |
665 |
MS+LRI |
2,3-Butanediol (Dimethylethylene glycol) |
chemical |
7.03. 104 ± 0.4. 104
|
nd |
nd |
817 |
743 |
MS+LRI |
1-hexanol |
fragrant, floral |
nd |
4.49. 104 ± 0.4. 104
|
nd |
881 |
861 |
MS |
3-Nonen-2-ol |
|
6.18. 104 ± 0.4. 104
|
nd |
nd |
929 |
- |
MS |
1,6-Octadien-3-ol, 3,7-dimethyl- (Linalool) |
citric, floral, floral citrus fragrant |
1.39. 105 ± 0.5. 103b
|
nd |
8.67. 105 ± 0.5. 105a
|
1110 |
1091 |
MS+LRI |
Phenylethyl Alcohol |
woody (woody-rose-honey), floral |
3.63. 106 ± 0.6. 106a
|
2.31. 106 ± 0.6. 105a
|
4.22. 106 ± 0.6. 105a
|
1137 |
1098 |
MS+LRI |
1-Nonanol |
citronella oil, citrus |
7.73. 105 ± 0.5. 105a
|
nd |
5.31. 105 ± 0.5. 104a
|
1186 |
1163 |
MS+LRI |
Esters
|
|
|
|
|
|
|
|
Propanoic acid, ethyl ester (Ethyl propanoate) |
sweet, fruity |
2.84. 103 ± 0.4. 103b
|
3.59. 104 ± 0.4. 103b
|
9.65. 105 ± 0.5. 105a
|
718 |
688 |
MR+LRI |
Butanoic acid, 2-methylbutyl ester |
fruity |
7.81. 106 ± 0.6. 106a
|
nd |
nd |
749 |
1044 |
MS |
Propanoic acid, 2-methyl-, ethyl ester (Isobutyric acid, ethyl ester) |
fruity, apple, banana, pineapple |
3.89. 105 ± 0.5. 105a
|
1.78. 105 ± 0.5. 103a
|
1.81. 105 ± 0.5. 104a
|
764 |
745 |
MS+LRI |
1-Pentanol, 2-methyl-, acetate |
|
nd |
4.34. 105 ± 8.50 |
nd |
779 |
984 |
MS |
Butanoic acid, ethyl ester (Ethyl butyrate) |
banana, pineapple |
3.06. 105 ± 0.5. 105a
|
1.04. 105 ± 0.5. 104a
|
2.16. 105 ± 0.5. 104a
|
801 |
787 |
MS+LRI |
2-Butenoic acid, ethyl ester, |
|
6.22. 104 ± 0.4. 104b
|
3.88. 104 ± 04. 104b
|
1.89. 105 ± 0.5. 104a
|
854 |
827 |
MS+LRI |
Butanoic acid, 2-methyl-, ethyl ester |
fruity, sweet, apple, banana, grape |
2.68. 104 ± 0.4. 104b
|
7.65. 104 ± 0.4. 103a
|
6.11. 104 ± 0.4. 103a,b
|
855 |
839 |
MS+LRI |
Butanoic acid, 3-methyl-, ethyl ester (Ethyl isovalerate) |
herbaceous, pineapple, grape, fruity, sweet |
5.39. 105 ± 0.5. 105a
|
1.71. 105 ± 0.5. 104b
|
1.08. 105 ± 0.5. 104b
|
859 |
840 |
MS+LRI |
1-Butanol, 3-methyl-, acetate (Isoamyl acetate) |
banana |
6.57. 105 ± 0.5. 105a
|
3.54. 105 ± 0.5. 104b
|
2.60. 105 ± 0.5. 104b
|
883 |
861 |
MS+LRI |
1-Butanol, 2-methyl-, acetate |
|
1.34. 105 ± 0.5. 104a
|
7.14. 104 ± 0.4. 102a,b
|
nd |
885 |
868 |
MS+LRI |
Hexanoic acid, ethyl ester (Ethyl hexanoate) |
fruity |
4.81. 106 ± 0.6. 106a
|
2.35. 106 ± 0.6. 105a
|
2.52. 106 ± 0.6. 106a
|
1005 |
985 |
MS+LRI |
Hex-4-enoic acid, ethyl ester |
|
3.34. 105 ± 0.5. 105
|
nd |
nd |
1008 |
- |
MS |
2-Hexenoic acid, ethyl ester |
|
1.46. 105 ± 0.5. 104a
|
7.47. 104 ± 0.4. 103b
|
nd |
1055 |
1040 |
MS |
Geranylvinyl ether |
herbaceous, floral, sweet anise |
nd |
8.41. 104 ± 0.4. 103
|
nd |
1070 |
1082 |
MS+LRI |
Propanoic acid, 2-hydroxy-, 3-methylbutyl ester (Isoamyl lactate) |
lactic, raspberry |
nd |
6.54. 104 ± 0.4. 104
|
nd |
1082 |
1084 |
MS+LRI |
Heptanoic acid, ethyl ester |
grape, fruity |
3.39. 105 ± 0.5. 105a
|
6.66. 104 ± 0.4. 104a
|
1.24. 105 ± 0.5. 104a
|
1105 |
1111 |
MS+LRI |
Butanedioic acid, diethyl ester (Succinic acid, diethyl ester) |
fruity, apple, strawberry |
4.37. 106 ± 0.6. 106a
|
1.54. 106 ± 0.6. 105a
|
3.56. 106 ± 0.6. 105a
|
1170 |
1149 |
MS+LRI |
Octanoic acid, ethyl ester (Ethyl caprylate) |
apple, vinous |
1.38. 105 ± 0.8. 104a
|
1.44. 105 ± 0.5. 104a
|
nd |
1180 |
1224 |
MS+LRI |
Benzeneacetic acid, ethyl ester |
|
nd |
6.60. 104 ± 0.4. 104
|
nd |
1270 |
- |
MS |
Decanoic acid, methyl ester |
|
1.45. 105 ± 0.5. 104
|
nd |
nd |
1333 |
1382 |
MS+LRI |
Decanoic acid, ethyl ester (Ethyl decanoate) |
fruit, oily, floral |
7.46. 106 ± 0.6. 106a
|
1.69. 106 ± 0.6. 106b
|
3.09. 106 ± 0.6. 106b
|
1398 |
1583 |
MS+LRI |
Dodecanoic acid, ethyl ester (Ethyl dodecanoate) |
fruit, oily, floral |
1.36. 105 ± 0.5. 104a
|
nd |
1.40. 105 ± 0.5. 104a
|
1590 |
1591 |
MS |
Hexadecanoic acid, ethyl ester (Ethyl hexadecanoate) |
|
nd |
nd |
5.77. 104 ± 0.4. 104b
|
1861 |
1990 |
MS |
Terpenes
|
|
|
|
|
|
|
|
Styrene (Cinnamol) |
sweet, cinnamon |
2.62. 105 ± 0.5. 104a
|
3.89. 104 ± 0.4.103b
|
nd |
903 |
890 |
MS |
1-Methyl-4-(1-methylethylidene)-1-cyclohexene (Terpinoloene) |
anise (fennel) oil, mint |
3.65. 105 ± 0.5. 105a
|
9.39. 104 ± 0.4. 104a
|
2.52. 105 ± 0.5. 105a
|
1028 |
1089 |
MS+LRI |
o-Cymene |
thyme essential oil |
1.12. 105 ± 0.5. 105a
|
1.44. 105 ± 0.5. 104a
|
nd |
1037 |
1022 |
MS+LRI |
Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (Limonene) |
citric, floral, green |
2.63. 105 ± 0.5. 105
|
nd |
nd |
1041 |
1028 |
MS+LRI |
2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene (α-Pinene) |
|
5.52. 104 ± 0.4. 104
|
nd |
nd |
1042 |
980 |
MS |
Eucalyptol |
eucalyptus oil |
8.99. 104 ± 0.65. 104a
|
5.83. 104E ± 0.4. 103a
|
9.04. 104 ± 0.9. 103a
|
1047 |
1030 |
MS+LRI |
4-Terpinenyl acetate |
|
5.85. 104 ± 0.4. 104a
|
3.79. 104 ± 0.4. 103a
|
nd |
1048 |
1270 |
MS+LRI |
α-Terpinene |
citrus, lemon, lime |
3.27. 105 ± 0.5. 105
|
nd |
|
1098 |
1015 |
MS |
3-Cyclohexene-1-methanol, α,α,4-trimethyl-, propanoate (α-Terpinyl propionate) |
|
nd |
nd |
2.66. 106 ± 0.6. 105
|
1214 |
- |
MS |
α-Terpineol |
lilac lily of the valley (floral) |
3.46. 105 ± 0.5. 103a
|
9.58. 104 ± 0.4. 104a
|
3.58. 104 ± 0.5. 103a
|
1224 |
1285 |
MS+LRI |
3-Cyclohexene-1-methanol, α,α,4-trimethyl-, acetate (α-terpineol, acetate) |
herbal, spicy, woody, floral, |
5.04. 105 ± 0.5. 105a
|
1.03. 105 ± 0.5. 104b
|
9.56. 104 ± 0.4. 103b
|
1264 |
- |
MS |
Naphthalene, 1,2-dihydro-1,1,6-trimethyl- |
yeast |
1.05. 105 ± 0.5. 104b
|
6.12. 105 ± 0.5. 105a
|
nd |
1392 |
1336 |
MS+LRI |
Aldehydes and Ketones
|
|
|
|
|
|
|
|
Methylglyoxal (Pyruvaldehyde) |
acid-sweet |
4.50. 104 ± 0.4. 104
|
nd |
nd |
<600 |
- |
MS |
Butanal, 3-hydroxy (Acetaldol) |
|
nd |
3.06. 105 ± 0.5. 105
|
nd |
<600 |
- |
MS |
2-Propanone, 1,1-diethoxy- (Pyruvaldehyde, 1-(diethylacetal)) |
|
nd |
7.52. 104 ± 0.4. 104
|
nd |
731 |
644 |
MS+LRI |
3-Hepten-2-one |
fruity, pineapple, passion fruit |
6.87. 104 ± 0.4. 103
|
|
nd |
794 |
- |
MS |
Ionone |
rose oil |
3.48. 106 ± 0.6. 105a
|
1.53E. 106 ± 0.6. 105b
|
2.17. 106 ± 0.6. 105a,b
|
1294 |
- |
MS |
Amines
|
|
|
|
|
|
|
|
Dimethylamine |
ammoniacal |
8.29E. 104 ± 0.4. 104
|
nd |
nd |
< 600 |
- |
MS |
Others
|
|
|
|
|
|
|
|
Thioaceticacid |
|
nd |
nd |
3.01E. 106 ± 0.6. 106
|
717 |
- |
MS |
trans-3-Methyl-4-octanolide (trans-Whiskeylactone) |
|
nd |
1.08. 105 ± 0.5. 104
|
nd |
827 |
- |
MS |
2H-Pyran, 2-ethenyltetrahydro-2,6,6-trimethyl- |
|
1.39. 105 ± 0.5. 105a,b
|
nd |
3.41. 105 ± 0.5. 105a
|
979 |
960 |
MS+LRI |
Secondary Volatile Compound (GC-FID)
|
Mean (mg.L-1) ± Standard deviation
|
QM
|
SB
|
MR
|
Acetaldehyde |
|
34.54 ± 8.50b
|
122.05 ± 8.02a
|
48.07 ± 9.87b
|
Ethyl acetate |
fruit |
nd |
40.83 ± 11.87a
|
47.72 ± 4.14a
|
Methanol |
|
164.95 ± 11.60a
|
141.48 ± 6.10a
|
80.17 ± 10.41b
|
1-propanol |
alcoholic, pungent |
nd |
29.89 ± 2.79a
|
18.96 ± 1.31b
|
2-methyl-1-butanol±3-methyl-1-butanol |
fruit |
111.35 ± 2.84a
|
80.35 ± 3.65b
|
86.55 ± 7.05b
|