In this study the relationship between the pH SMP and H + Al concentrations was evaluated, in order to establish an equation for estimating the potential acidity of soils from Northeastern Brazil. The H + Al concentration (calcium acetate 0.5 mol L-1, pH 7.0) and pH SMP were analyzed in 81 soil samples. Soil carbon content ranged from 1.8 to 35.6 g kg-1, and clay content varied from 60 to 590 g kg-1. The equation H + Al = 31.521(pH SMP)² -451.61 pH SMP + 1625.3 (R² = 0.87**), with H + Al in mmol c dm-3, provides a good estimation of potential acidity by using the pH SMP.
soil pH; buffer solution; hydrogen; exchangeable aluminum