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Journal of the Brazilian Chemical Society

Print version ISSN 0103-5053On-line version ISSN 1678-4790

J. Braz. Chem. Soc. vol.20 no.2 São Paulo  2009

https://doi.org/10.1590/S0103-50532009000200004 

ARTICLE

 

Influence of sources and meteorology on surface concentrations of gases and aerosols in a coastal industrial complex

 

 

Andrew G. AllenI, *; Andrew J. S. McGonigleII; Arnaldo A. CardosoI; Cristine M. D. MachadoI; Brian DavisonIII; Willian C. PaterliniI; Gisele O. da RochaIV, # ; Jailson B. de AndradeIV, V

IInstituto de Química, Universidade Estadual Paulista, CP 355, 14800-900 Araraquara-SP, Brazil
IIDepartment of Geography, University of Sheffield, Sheffield, S10 2TN, United Kingdom
IIIDepartment of Environmental Science, Lancaster University, Lancaster, LA1 4YQ, United Kingdom
IVCentro Interdisciplinar em Energia e Ambiente, Universidade Federal da Bahia, 40110-040 Salvador-BA, Brazil
VInstituto de Química, Universidade Federal da Bahia, Campus Universitário de Ondina, 40170-029 Salvador-BA, Brazil

 

 


ABSTRACT

Industrial emissions are a notorious source of atmospheric pollution in the Cubatão industrial park of Southern Brazil, where dispersion is restricted by surrounding mountain ranges. It is shown here that road transport is also a large source of gases and aerosols, which can dominate pollutant concentrations at ground level, depending on meteorological conditions. SO2 was released mainly by industry, while road transport was a major source of NOx. Rapid removal of NO2 and SO2 was attributed to fast gas phase and heterogeneous reactions, respectively. Average PM10 concentrations increased by an order of magnitude during sea breeze fumigation, and high particulate pollution events were associated with vehicular activity. It is demonstrated that fast-response portable instrumentation can provide a useful alternative to measurements at fixed network sites for spatial (horizontal and vertical) mapping of atmospheric pollutants.

Keywords: NO2, SO2, PM10, industry, transport, meteorology


RESUMO

Emissões industriais são as fontes principais de poluição atmosférica no parque industrial de Cubatão, no sudeste do Brasil, onde a dispersão é limitada pela extensa faixa de montanhas na região. O transporte de veículos pesados é uma fonte importante de gases e aerossóis e pode influenciar nas concentrações de poluentes atmosféricos próximos à superfície, dependendo das condições meteorológicas. Este trabalho mostra que as fontes industriais foram predominantes nos fluxos de SO2, enquanto que o transporte veicular foi a principal fonte de NO2 para a atmosfera. A rápida remoção de NO2 e SO2 da atmosfera foi atribuída às reações na fase gasosa e reações heterogêneas, respectivamente. Concentrações médias de MP10 aumentaram cerca de uma ordem de magnitude durante a circulação da brisa do mar. Foi demonstrado que instrumentação de resposta rápida pode fornecer uma alternativa conveniente às medidas obtidas com equipamentos fixos para mapeamento espacial (horizontal e vertical) de poluentes atmosféricos.


 

 

Introduction

The metropolis of São Paulo, together with its satellite cities and the adjoining coastal strip, constitutes the largest urban-industrial complex in the southern hemisphere. Anthropogenic emissions cause near-continuous photochemical pollution, with downwind production of secondary particulates and ozone. Cubatão (23º53"S, 46º25"W), at sea level 40 km from São Paulo (760 m a.s.l.), is one of nine municipalities comprising the Baixada Santista metropolitan area (population ca. 1.5 million), and is host to the region's densest installation of heavy industry. The industrial complex includes 10 chemical and petrochemical, 7 fertilizer and 1 each of gypsum, cement, steel and paper manufacturing plants, plus approximately one hundred smaller units. Emissions inventories show that annual emissions of SO2 (ca. 2.1 × 104 T yr-1) and NOx (ca. 1.8 × 104 T yr-1) from these installations are similar to those from industrial sources within the São Paulo metropolitan region.1 Inland dispersal of pollutants is restricted by topography, as the industrial plants are located at the base of a ca. 900 m coastal mountain range. During the daytime, gases and aerosols accumulate within a sea breeze circulation, while at night the ground level wind direction reverses, with heavily polluted air draining from the valleys, and air from the São Paulo plateau flowing towards the coast. The level of pollution is sufficient to cause damage to adjacent Atlantic rain forest ecosystems2-4 and human health.5,6

In this paper, we report on an observation-based evaluation of the sources, transport and dispersion of SO2, NO2 and aerosols in the Baixada Santista air basin, using open path optical spectroscopy combined with in-situ measurements.

 

Experimental

Field sites

Fieldwork was conducted during November 25th-28th 2004, in and around Cubatão and the associated industrial complex, at the sites shown in Figure 1. Atmospheric column concentrations of SO2 and NO2 were measured, together with ground-level NO, NO2 and aerosol number concentrations, in the lower Rio Mogi valley, ca. 1 km distant from the industrial installations, and upwind of emissions during down-slope airflow. Additional measurements throughout the industrial park were made with instruments installed on a car roof. Vehicle traverses under the plumes allowed calculation of the total emission fluxes of NO2 and SO2 from the complex. SO2, NO2, O3 and PM10 were measured at the São Paulo State Environment Agency (CETESB) automated network stations in central Cubatão, and in Vila Parisi, adjacent to the industrial area.

 

 

UV-Vis spectrometer

Atmospheric column amounts (defined as the product of concentration per unit volume and vertical depth, with units of ppm m) of SO2 and NO2 were determined using a miniature UV-Vis spectrometer (S2000, Ocean Optics Inc., USA) fibre-coupled to a telescope, providing a 20 mrad field of view of the zenith sky.7-9 Power was delivered via USB connection to a notebook computer running Ocean Optics OOIBase 32 acquisition software. Spectral integration times varied from 1s to 10s, depending on available light intensities, and each spectrum was georeferenced using the output from a hand held GPS receiver. The telescope was attached to a vertical pole, mounted to a vehicle. Sample data were collected whilst either stationary or during mobile measurements throughout the industrial park. Vehicle speed (ca. 20-30 km h-1) was not critical since the measurement procedure required the acquisition of geographically resolved column concentrations (rather than temporally resolved concentrations). These were calculated according to established differential optical absorption spectroscopy (DOAS) procedures,10,11 using DOASIS software (University of Heidelberg). Downwind transects at the industrial park perimeter and perpendicular to the wind direction permitted calculation of emission fluxes by integrating the column concentrations over the width of the industrial park plume, and multiplying by mean wind speed. These measurements were made at distances of 0.5-3.0 km from industrial stacks, equivalent to individual plume travel times (between the points of emission and measurement) of 2.5-25.0 minutes. Road transport-related emissions travel times were of similar order. Error in each gas emission rate measurement was estimated at ±22 %, accounted for by 10% uncertainty in the spectral column amount retrievals, and 20% error in the wind speed determinations.

In-situ gas measurements

Ground level concentrations of nitric oxide (NO) and nitrogen dioxide (NO2) were determined at the Rio Mogi site by sampling ambient air, at a flow rate of 0.8 L min-1, onto two C18 silica cartridges treated with a solution of 11% triethanolamine15 and connected in series. A small glass tube containing chromium trioxide (CrO3) glass beads, to convert NO to NO2, was placed in line between the two C18 cartridges. Following sample collection, the cartridges were extracted into deionized water and analyzed using the Griess-Saltzman technique.16

NO2, SO2 and O3 were measured at the Cubatão and Vila Parisi automatic network stations using chemiluminescence, pulsed UV fluorescence and UV absorption analyzers, respectively.1

Aerosol measurements

Aerosol number concentrations (1 minute averages), in a total of 15 size bins, were measured using a Grimm Aerosol Spectrometer (Model 1.108, Grimm Aerosol Technik GmbH, Ainring, Germany).7 In this device, ambient air was pumped at 1.2 L min-1 through a detector cell, illuminated by a semiconductor laser, generating a scattered light signal in proportion to the size of the scattering aerosol particles. Ambient temperature and humidity were measured using a Grimm Model 1.154 sensor connected to the spectrometer. Particulate mass concentrations (PM10) were subsequently calculated from the raw counts, by assuming that the aerosols were spherical, aqueous, and had a density of 1.2 g cm-3: a conservative estimate for ambient aerosols.12-14

PM10 mass concentrations were measured at the Cubatão and Vila Parisi automatic network stations using Thermo/Andersen Model FH62C14 β-attenuation instruments.1

 

Results and Discussion

Meteorology

A high-pressure system between November 25th and 27th moved northwards after November 28th, following arrival of a cold front and more changeable weather with persistent rain. Daily sea breeze formation caused reversals of surface wind direction, from NNE to SSW to NNE, with the arrival of the sea breeze front in the early afternoon being signaled by an immediate decrease in visibility (due to its high aerosol content). During the evening, retreat of the circulation cell was accompanied by a return to down-slope airflow from around 20:00 pm. The depth of the local sea breeze cell in this region has been reported to be ca. 600-800 m, and that of the nighttime down-slope flow ca. 200-300 m.17,18 Mean wind speeds, measured (under sea breeze conditions) at the Cubatão automatic network station during the periods of acquisition of data for emission flux calculations, were 2.6 m s-1, 2.0 m s-1 and 3.2 m s-1 on November 25th, 26th and 27th, respectively. These were similar to wind speeds estimated using time-lapse photography of stack plumes (2.0-3.0 m s-1) on these days, and were therefore considered representative of wind speeds to at least 50 m altitude. Nonetheless, since emissions flux estimates are, in part, a function of wind speed, and full vertical wind speed profiles were not available, allowance is made for possible error of ca. ±20% in wind speeds used in the flux calculations.

Emission fluxes of SO2 and NO2

Fluctuations in SO2 and NO2 column concentrations measured at ground level reflected the geographical distributions of stack emissions and road traffic density. Emission flux rates calculated from data acquisitions during downwind transects (Figure 2) were 0.40 ± 0.088 kg (SO2) s-1 and 0.20 ± 0.044 kg (NO2) s-1 on November 25th, 0.71 ± 0.14 kg (SO2) s-1 and 0.15 ± 0.033 kg (NO2) s-1 on November 26th, and 0.65 ± 0.16 kg (SO2) s-1 and 0.03 ± 0.007 kg (NO2) s-1 on November 27th. The indicated flux ranges reflect a combined uncertainty of ±22% associated with the spectrometric and wind speed measurements. Considering all measurement days, overall mean emission fluxes from the Cubatão complex were 0.59 ± 0.13 kg (SO2) s-1 and 0.13 ± 0.029 kg (NO2) s-1. Annual inventory emissions from Cubatão's installations for 2004 were 20,750 T yr-1 (SO2) and 18,340 T yr-1 (NOx),1 equivalent to fluxes of 0.66 kg (SO2) s-1 and 0.58 kg (NOx) s-1. The SO2 flux is in good agreement with the present estimate. The difference between the inventory NOx emission (which did not consider any contribution from road transport sources) and the measured NO2 flux can be explained by the presence of nitric oxide (NO), which was not determined, and by rapid removal of NOx by reaction (discussed below).

 

 

NO2 production and removal

NO is converted to NO2 at a rate dependent on factors including meteorological conditions, and ozone and hydrocarbon contents of the transported air mass.19,20 During the daytime, reactions 1-3 describe the Leighton relationship, whereby ozone is formed and recycled:

Net NO2 production follows reaction of NO with the hydroperoxy and alkylperoxy free radicals formed during oxidation of organic compounds:

Hydrocarbon emissions of 3.46 × 104 T yr-1 from road transport (derived from population and fleet statistics) and 0.39 × 104 T yr-1 from industry1 should ensure an ample supply of free radical precursors, and hence the necessary conditions for rapid NO2 production. On consecutive days, there was a progressive decrease in the NO2 column concentration, relative to the SO2 column concentration; NO2/SO2 column ratios were 0.70, 0.29 and 0.06 on November 25th, 26th and 27th, respectively. The SO2 column concentration remained quite stable over the period, so that an explanation is required for the faster loss of NO2.

The column concentrations ratio was positively correlated with ozone and negatively correlated with relative humidity (Figure 3). The influence of ozone can be explained by the more rapid gas phase oxidation of NO by hydroperoxy and alkylperoxy free radicals, produced by reaction of ozone with hydrocarbons. There are several possible explanations for the relationship with relative humidity. Reactions removing nitrogen oxides from the atmosphere via heterogeneous processes on surfaces generate products including nitrates and nitrous acid (HONO).21,22 Experiments under controlled conditions suggest that the principal reaction could be that between water and NO2, with absorption of NO2 being dependent on the surface to volume ratio of particles possessing an aqueous surface film:23-25

 

 

Hence, relative humidity has a fundamental influence on formation of the aqueous film surrounding particles, which in the presence of high number concentrations of fine pollution aerosols acts to accelerate the conversion of NO2 to nitrous acid.24 Increased relative humidity also favours analogous reactions occurring in water droplets,23 on the surfaces of soil25 and on vegetation.26 Furthermore, ozone photolysis (reactions 8, 9) is linked to water vapour availability, with the reaction of NO2 with OH producing nitric acid and representing an irreversible loss of NO2 (10):

It can be concluded that rapid loss of NO2 was associated with high insolation and humidity, and elevated concentrations of free radicals produced during oxidation of hydrocarbons. Although heterogeneous surface reactions may have also contributed to NO2 removal, a trend of decreasing aerosol surface area (PM10 fraction) over the three sampling days suggests that gas phase reactions were most important.

Aqueous phase SO2 oxidation

Ground level SO2 concentrations (mean of all sites) during daytime fumigation were 15.2 ppb and 2.9 ppb on November 25th and 27th, respectively. The much lower ground level concentration on November 27th did not mirror either the SO2 column concentration or the industrial emission source strength (which was 0.40 kg (SO2) s-1 on the 25th, and 0.65 kg (SO2) s-1 on the 27th). A mechanism was therefore required to explain the faster SO2 loss on the 27th. Since observed SO2 column concentrations in the proximal plumes did not decline over the period (in contrast to NO2 column concentrations), elimination of SO2 was substantially slower than of NO2. Nonetheless, its removal rate increased when ozone and relative humidity increased.

Considering only reaction with the hydroxyl radical, under background atmospheric conditions SO2 and NO2 lifetimes are around 13 days and 16 h, respectively.27 In polluted air masses, lifetimes can be much shorter, and on the order of several hours for SO2.28,29 While gas phase reactions are important for removal of NO2, liquid phase reactions, involving ozone and hydrogen peroxide, are normally the most important reactive sink for SO2. Loss rates increase approximately in proportion to the available volume of aqueous droplets or aerosols.30 Taking into account the different daily SO2 emission fluxes, and ignoring any influence of droplet chemical composition, the difference in ground level SO2 concentrations on the two days would, in theory, require an increase of aqueous aerosol volume by a factor of ca. 8.5, near to the upper limit for atmospheric aerosol hygroscopic growth.31 This mechanism could not explain the SO2 loss, since aerosol volume decreased progressively throughout the consecutive sampling days, which suggests that solution chemistry and/or increased oxidant availability were the main factors influencing SO2 removal. The quantitative reduction in the ground level concentration on November 27th means that liquid phase reactions removed SO2 on a timescale similar to that required for transport aloft of plume emissions over the coast, and return at lower altitude. Given a mean measured wind speed of 3.2 m s-1, and an air mass transport distance of ca. 30 km, the SO2 lifetime under these conditions was ca. 2.6 h.

Contributions of industry and road transport to ground level SO2 and NOx

24 h mean SO2 concentrations in Vila Parisi were 5.7 ppb and 1.1 ppb on November 25th and 27th, respectively (no data were available for November 26th). SO2 concentrations in Cubatão were 9.2 ppb, 5.3 ppb and 1.5 ppb on November 25th, 26th and 27th, respectively. Corresponding NO2 concentrations in Vila Parisi were 69.7 ppb and 44.7 ppb, and in Cubatão were 39.9 ppb, 35.6 ppb and 21.3 ppb. Ground level afternoon concentrations of NO and NO2 at the Rio Mogi site were 0.9 ppb and 11 ppb on November 26th, and 1.4 ppb and 17.2 ppb on November 27th, demonstrating that at ground level away from the immediate vicinity of emission sources NO2 concentrations were around an order of magnitude higher than those of NO. SO2 concentrations were higher in Cubatão than in Vila Parisi, while conversely NO2 concentrations were higher in Vila Parisi. These observations can be explained by the combined influences of emission sources and meteorology, since there is intense road transport movement near the Vila Parisi site, while Cubatão is downwind of large industrial SO2 emitters, including oil refineries, during down-slope airflow towards the ocean (in the absence of the sea breeze, at night and during the morning).

In order to further investigate the relative influences of stack and ground level emissions, hypothetical atmospheric concentrations of SO2 and NO2, which would result from complete vertical mixing and homogeneity through a 700 m mixed layer, were calculated from the column integrated measurements (note: complete vertical mixing was not achieved in practice). The mean SO2 concentrations (ppb) thus derived were 40.3, 42.2 and 31.7 for November 25th, 26th and 27th, respectively. The corresponding values for NO2 were 17.7, 10.5 and 5.7. These values were either higher (SO2) or lower (NO2) than those from the ground level monitoring stations, showing that there was a predominance of high level (stack) emissions of SO2, and ground level (road transport) emissions of NOx. Correlation between SO2 and NO2 column concentrations measured throughout the industrial complex (Figure 4) results from the co-existence of strong sources of both gases in the study area, irrespective of emission altitude. However, NO2 rich columns were observed near truck parks or adjacent to the entrances of industrial facilities, where vehicular movements were especially intense. Average inventory NOx/SO2 concentration ratios were 24 and 1.2 for vehicle exhaust (São Paulo metropolitan area), and industrial emissions (Cubatão), respectively. A mean ground level NO2/SO2 ratio of 9.3 (for Vila Parisi and Cubatão) reflects the greater road transport emission of NOx relative to SO2. Hence, inventory estimates of NOx emissions from the Cubatão complex, which consider only industrial sources and ignore the influence of road transport, would need to be revised upwards to reflect total NOx production.

 

 

Current (2008) Brazilian primary and secondary air quality standards for SO2 are 365 µg m-3 and 100 µg m-3 (equivalent to 140 ppb and 40 ppb) for 24 h means, not to be exceeded more than once per year, and 80 µg m-3 and 40 µg m-3 (30 ppb and 15 ppb) for annual arithmetic means. The primary and secondary standards for NO2 are 320 µg m-3 and 190 µg m-3 (170 ppb and 100 ppb) for 1 h means, not to be exceeded more than once per year, and 100 µg m-3 (50 ppb) for the annual arithmetic mean.32 The measurements at the stationary sites are therefore indicative of compliance with these air quality standards.

Sources of particulates

A correlation coefficient (r) of 0.79 (n = 80, p < 0.01) was obtained between SO2 and NO2 column concentrations; however, no significant correlations were obtained between simultaneous measurements of ground level particle number concentrations, and SO2 and NO2 column concentrations, with coefficients (r) of 0.00 and 0.12 (n = 80, p > 0.1) obtained, respectively. The slightly higher correlation coefficient obtained between NO2 columns and aerosols (than between SO2 columns and aerosols) can be explained by co-emission of NO2 and aerosols from the road transport source. Lack of correlation between SO2 columns and aerosols reflects the existence of multiple particle sources including fugitive dust from cement and steel works, dust resuspension, vehicles and sea salt, in addition to emissions from the stacks of large combustion plants. Particles emitted from stacks arrived at ground level following transport aloft towards and over the ocean in the sea breeze circulation, and the return inland of the aerosol-laden air mass at lower altitude. Figure 5 shows the step change in aerosol number concentration at the time of first arrival of the sea breeze cell at the Rio Mogi site on November 28th.

 

 

Current Brazilian PM10 standards are 50 µg m-3 (annual arithmetic mean) and 150 µg m-3 (24 h mean, not to be exceeded more than once per year). During clean down-slope flow in the Rio Mogi valley, the mean total particle number concentration was 1.7 × 104 L-1 and the mean PM10 mass concentration (conservative estimate based on a particle density of 1.2 g cm-3) was 3.6 µg m-3. During fumigation, mean number concentrations were 1.9 x 105 L-1 in the Mogi valley, and 7.2 x 104 L-1 in residential areas of Cubatão, approximately ten and four times higher than background, and equivalent to PM10 values of 40 µg m-3 and 15 µg m-3, respectively, similar to 24 h means at the Cubatão network site (33-52 µg m-3). Within the industrial park, under fumigation conditions daily mean PM10 concentrations (mobile measurements) ranged between 61-195 µg m-3, in close agreement with measurements at the fixed site in Vila Parisi (58-157 µg m-3). 46% of all one-minute mean mobile PM10 measurements exceeded 50 µg m-3, and 14% exceeded 150 µg m-3. Locally, particulate concentrations reached extremely high levels (PM10 < 4260 µg m-3), notably in truck maneuvering and loading areas adjacent to industries, due to the combined contributions of sea breeze-entrained stack emissions, exhaust particulates and re-suspended dusts. These data signal a potential health concern, not only due to the high particulate mass concentrations throughout much of the industrial complex, but also because ~45% of the aerosol mass resided in the fine particulate fraction (< 3.5 µm), which can be readily inhaled and deposited in the human respiratory system. Under background conditions, the fine fraction contributed only 24% of the aerosol mass (and total mass concentrations were much lower).

 

Conclusions

Atmospheric pollution in the Baixada Santista region is a function of the interaction between spatially variable industrial and road transport sources, and daily fumigation induced by the geographically constricted sea breeze. There is non-uniformity in vertical gas concentration profiles, with industrial stacks releasing more SO2, and vehicles more NOx. Very high particulate concentrations at ground level were due to vehicle activity. Emissions inventories do not currently include road transport NOx, leading to an underestimation of the total NOx emission. Accelerated chemistry in the air masses caused rapid oxidation of pollutants in gas and aerosol/droplet phases, with gas phase and heterogeneous processes predominating for NO2 and SO2, respectively.

Data from fixed network monitoring stations were generally reflective of atmospheric concentrations across this region, and can reliably provide information concerning long-term trends in pollutant concentrations. Although instruments at fixed sites may be unable to detect localized pollution, especially during periods of downslope airflow, data from these are more representative of the wider region under sea breeze conditions, when there is greater air mass mixing. Future use of directional sampling and chemical source apportionment would assist in identification of specific sources, and aid in development of mitigation strategies aiming to protect human health, especially of individuals working directly in the transport and distribution sector.

 

Acknowledgments

The authors thank the staff of CETESB, Cubatão, for logistical support. The work was funded by grants from CNPq, FAPESP, FUNDUNESP, FAPESB and the British Council in Brazil. AM acknowledges a RCUK academic fellowship.

 

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Received: July 7, 2008
Web Release Date: December 4, 2008
FAPESP helped in meeting the publication costs of this article.

 

 

* e-mail: andrew@pq.cnpq.br
# Present Address: Instituto Multidisciplinar de Saúde, UFBA, Campus Universitário Anísio Teixeira, 45055-090, Vitória da Conquista-BA, Brazil

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